| Alkaline Electrolyzer |
Electricity and water |
An alkaline electrolyte transfers hydroxide ions between electrodes while electricity splits water into hydrogen and oxygen. |
Approximately 60–90°C |
Approximately 60–75% on a lower-heating-value basis |
No direct carbon emissions when supplied with renewable electricity; indirect emissions depend on the electricity source. |
Large stationary hydrogen production, industrial gas supply and energy storage. |
| Proton Exchange Membrane (PEM) Electrolyzer |
Electricity and purified water |
A proton-conducting membrane allows hydrogen ions to pass through while oxygen is released at the anode and hydrogen is formed at the cathode. |
Approximately 50–80°C |
Approximately 55–70% on a lower-heating-value basis |
No direct carbon emissions when powered by renewable electricity; indirect emissions vary with the grid mix. |
Renewable-energy balancing, variable-load operation, refueling stations and compact installations. |
| Solid Oxide Electrolyzer (SOEC) |
Electricity, water and high-temperature heat |
A ceramic electrolyte conducts oxygen ions at high temperature. Steam is reduced at the electrode to produce hydrogen. |
Approximately 650–850°C |
Potentially above 80% when suitable process heat is available |
Emissions depend on the electricity and heat sources; no direct carbon emissions from water splitting alone. |
Industrial facilities with available high-temperature heat and integrated hydrogen production. |
| Steam Methane Reforming (SMR) |
Natural gas, steam and process heat |
Steam reacts with methane at high temperature to form synthesis gas, followed by a water-gas-shift reaction and hydrogen purification. |
Approximately 700–1,000°C |
Approximately 65–75% for the hydrogen-production process |
Typically about 9–12 kg of carbon dioxide per kg of hydrogen without carbon capture; actual values vary by plant and gas source. |
Large-scale industrial hydrogen production and refinery operations. |
| SMR with Carbon Capture |
Natural gas, steam and process heat |
Hydrogen is produced through steam reforming, while a carbon-capture system separates part of the resulting carbon dioxide for transport or storage. |
Approximately 700–1,000°C |
Generally lower than conventional SMR because capture requires additional energy |
Lower process emissions than conventional SMR, but residual emissions and upstream methane emissions may remain. |
Large hydrogen plants where carbon transport and geological storage are available. |
| Biomass Gasification |
Biomass, oxygen or steam, and process heat |
Biomass is converted at high temperature into synthesis gas, which is then cleaned, shifted and purified to obtain hydrogen. |
Approximately 700–1,200°C |
Varies widely, commonly around 35–55% for the overall conversion process |
Carbon dioxide and other pollutants can be produced; lifecycle emissions depend on feedstock sourcing and land-use practices. |
Projects using agricultural residues, forestry residues or other sustainable biomass resources. |
| PEM Fuel Cell Generator |
Hydrogen and air |
Hydrogen is oxidized at the anode, oxygen is reduced at the cathode, and the resulting electrochemical reaction produces electricity, heat and water. |
Approximately 60–80°C |
Approximately 40–60% electrical efficiency |
Water and heat at the point of use; lifecycle emissions depend on how the hydrogen is produced. |
Backup power, portable power, vehicles and distributed electricity generation. |
| Solid Oxide Fuel Cell Generator |
Hydrogen, or certain hydrogen-rich fuels after internal processing, and air |
A solid ceramic electrolyte conducts oxygen ions at high temperature, producing electricity through an electrochemical reaction. |
Approximately 600–1,000°C |
Approximately 50–65% electrical efficiency; higher total efficiency is possible with combined heat and power. |
Very low pollutants when operated on hydrogen; emissions vary if a carbon-containing fuel is internally reformed. |
Stationary distributed generation, microgrids and combined heat-and-power systems. |